Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2 N 3,S}palladium(II) N,N-dimethylformamide disolvate
نویسندگان
چکیده
In the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The Pd(II) ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethyl-formamide (DMF) solvent mol-ecules via an N-H⋯O inter-action. In addition, C-H⋯S inter-actions are observed.
منابع مشابه
Bis{benzyl N′-[(1H-indol-3-yl)methylene]dithiocarbazato-κ2 N′,S}copper(II) N,N-dimethylformamide disolvate
In the structure of [Cu(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Cu atom (site symmetry ) is N,S-chelated by the two deprotonated Schiff-base anions that define a distorted square-planar geometry. An N-H⋯O hydrogen bond links the mononuclear complex to the DMF solvent mol-ecules.
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The Pd(II) ion in the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent mol-ecules via an N-H⋯N inter-...
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In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Ni atom (site symmetry ) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the crystal structure, an N-H⋯O hydrogen bond links the complex to the dimethyl-formamide solvent mol-ecule.
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